138753-38-5Relevant academic research and scientific papers
Control of Chemoselectivity in the Rhodium(II)-Catalyzed Alkyne Insertion Reaction of α-Diazo Ketones
Padwa, Albert,Austin, David J.,Xu, Simon L.
, p. 1330 - 1331 (1992)
Chemoselectivity in the rhodium(II) catalyzed reaction of an acetylenic α-diazo ketone was found to be markedly influenced by the solvent used.Cyclopropenyl indenones are formed in pentane whereas alkenyl-substituted indenones are produced when CH2Cl2 is
Cyclization Reactions of Rhodium Carbene Complexes. Effect of Composition and Oxidation State of the Metal
Padwa, Albert,Kassir, Jamal M.,Xu, Simon L.
, p. 1642 - 1652 (2007/10/03)
Treatment of o-(1,7-octadiynyl)benzoyldiazoethane with rhodium(II) octanoate in pentane resulted in a double internal/internal alkyne insertion reaction producing a labile bicyclo[4.1.0]hept-1(7)-ene derivative which readily undergoes a Diels-Alder reacti
