138784-89-1

Upstream product

• 1079-66-9 chloro-diphenylphosphine 
• 95-13-6 1-indene 

Downstream Products

• 718638-85-8 3-(diphenylphosphino)-1-(trimethylsilyl)indene 
• 233275-66-6 bis(1-diphenylphosphinoindenyl)iron(II) 
• 909702-90-5 meso-bis(1-(diphenylphosphino)-η5-indenyl)iron(II) 
• 927912-42-3 [(κ1-P-C9H7PPh2)AuCl] 
• 1286207-48-4 [Ru3(μ2-H)(μ3-3-Ph2PC9H6)(CO)9] 
• 138784-95-9 {PtCl₂((C₉H₇)P(C₆H₅)2)2} 
• 718639-30-6 meso-bis(1-(diphenylphosphino)-4,7-dimethyl-η5-indenyl)iron(II) 
• 138784-95-9 {PtCl₂((C₉H₇)P(C₆H₅)2)2} 

Relevant academic research and scientific papers

Synthesis of (indenylidene)phosphoranes - A novel class of ligand precursors for main-group and transition metal organometallics

IndPPh2 (1) reacts with RCH2Br to form the phosphonium salts [RCH2P(Ph)2Ind]+Br - (2: R = Ph; 3: R = C6F5) in high yields. Oxidation of 1 with H2O2 in THF proceeds smoothly to give the phosphane oxide IndP(O)Ph2 (4). Dehydrobromination of 2 and 3 with NaH in THF yields the corresponding indenylidenephosphoranes C 9H6=P(Ph)2CH2R (5: R = Ph; 6: R = C6F5). Further deprotonation of 6 with excess NaH results in formation of sodium 1-{[(pentafluorophenyl)methylidene]diphenylphosphoranyl} indenide (7), isolated as a solvate with three THF molecules. A detailed NMR study of new ligand precursors and X-ray structure studies of 5 and 7 have been accomplished. A short F→Na coordination contact in the molecular structure of 7 has been detected. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.