138785-92-9Relevant academic research and scientific papers
Alkyliron and Alkylcobalt Reagents, IV.- Aldehyde-Selective Cyanoalkylation with Cyanalkyl Derivatives of Iron(II) and Other Transition Metals
Kauffmann, Thomas,Kieper, Hansjoerg,Pieper, Hans
, p. 899 - 906 (2007/10/02)
For the transfer of the cyanomethyl residue with high aldehydes vs. ketone selectivity, the Fe reagent 3a is a good alternative to the known Ti reagent 1a, whereas analogous reagents with the metals Mn, Co, Ni or Cu are unfavorable.For the aldehyde- vs. k
