1388136-23-9Relevant academic research and scientific papers
Divergent construction of nitrogen-containing polycyclic compounds with a dearomatization strategy
Wang, Linfei,Fan, Renhua
supporting information; experimental part, p. 3596 - 3599 (2012/08/28)
The oxidative dearomatization of para-substituted o-alkynylanilines afforded 2-alkynyl cyclohexadienimines, which can act as active substrates for reaction with electron-rich styrenes. The reaction is metal-controlled. Bi(OTf)3-catalyzed reactions afforded 3,4-dihydro-cyclopenta[c,d] indoles, and AgOTf-catalyzed reactions provided tricyclic pyrrole derivatives.
