138827-07-3

Basic information

• Product Name: tricarbonyl(η6-o-methylbiphenyl)chromium(0)
• CAS NO: 138827-07-3
• Molecular Weight: 304.265
• Mol File: 138827-07-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: tricarbonyl(η6-o-methylbiphenyl)chromium(0)(CAS DataBase Reference)
• NIST Chemistry Reference: tricarbonyl(η6-o-methylbiphenyl)chromium(0)(138827-07-3)
• EPA Substance Registry System: tricarbonyl(η6-o-methylbiphenyl)chromium(0)(138827-07-3)

Safety Data

• Hazardous Substances Data: 138827-07-3(Hazardous Substances Data)

Upstream product

• 12111-60-3 (biphenyl)tricarbonylchromium 
• 12082-05-2 (η6-fluorobenzene)tricarbonylchromium 
• 16419-60-6 2-Methylphenylboronic acid 

Relevant articles and documents

Palladium catalysed cross-coupling of (fluoroarene)tricarbonyl-chromium(o) complexes

(Fluoroarene)tricarbonylchromium(o) complexes were found to undergo Suzuki and Stille cross-coupling reactions to form functionalised biaryl and styrene complexes in up to 87 and 52% yields, respectively. The Suzuki reactions were optimal with dipalladium tris(dibenzylideneacetone)-trimethylphosphine-caesium carbonate in DME at reflux. The Stille reactions were optimal with dipalladium tris(dibenzylideneacetone)-trimethylphosphine-caesium fluoride in DME at reflux and neither was adversely affected by a methoxy group on the complexed ring. The Suzuki reaction tolerated a chloro group on the arylboronic acid ring but not a bromo group. The Royal Society of Chemistry 2000.

Regioselective Nucleophilic Additions to Tricarbonyl(η6-arene)chromium(0) complexes: Electronic versus Chelation Control

Regioselective addition of t-butyl-lithium to tricarbonyl(η6-benzyl alcohol)chromium(0) proceeds to give tricarbonyl(η6-5-methylene-6-exo-t-butylcyclohexa-1,3-diene)chromium(0), which can be isomerised to tricarbonyl(η6-o-