138827-41-5

Basic information

• Product Name: Rh(H)(CO)(P{C₆H₅}3)(P{OC₆H₅}3)2
• CAS NO: 138827-41-5
• Molecular Weight: 1014.79
• Mol File: 138827-41-5.mol

Chemical Properties

• CAS DataBase Reference: Rh(H)(CO)(P{C₆H₅}3)(P{OC₆H₅}3)2(CAS DataBase Reference)
• NIST Chemistry Reference: Rh(H)(CO)(P{C₆H₅}3)(P{OC₆H₅}3)2(138827-41-5)
• EPA Substance Registry System: Rh(H)(CO)(P{C₆H₅}3)(P{OC₆H₅}3)2(138827-41-5)

Safety Data

• Hazardous Substances Data: 138827-41-5(Hazardous Substances Data)

Upstream product

• 101-02-0 triphenyl phosphite 

Relevant articles and documents

1,5-Hexadiene selective hydroformylation reaction catalyzed with Rh(acac)2/P(OPh)3 and Rh(acac)(CO)(PPh3)/PPh3 complexes

Hydroformylation of 1,5-hexadiene, catalyzed by the system Rh(acac)2/P(OPh)3 (I), leads to the formation of mono- and dialdehydes, 4-heptenal, 2-Me-3-hexenal and octane-1,8-dial, 2,5-Me2-hexanedial respectively.The yield of dialdehydes increases with temperature and pressure and reaches 100percent at 80 deg C and 10 atm of CO/H2 = 1.The reaction catalyzed by Rh(acac)(CO)(PPh3)/PPh3 (II) system produces, besides dialdehydes, monoaldehydes with a terminal double bond, namely 6-heptenal and 2-Me-5-hexenal.The migration of the double bonds in monoaldehydes dependsmainly on the donor properties of modifying ligands.Phosphine when used as a modifying ligand (II), because of its strong donor properties, restricts isomerization (double bond migration) and diminishes yield of 4-heptenal.In contrast, when less strongly donating ligands such as phosphite are used as modifying ligands (I), independently of its steric properties, 4-heptenal is the main reaction product.Key words: Hydroformylation; Rhodium; Hexadiene; Catalysis