138836-01-8

Basic information

• Product Name: Cyclopropanol, 2-methyl-1-pyrazinyl-, cis-
• CAS NO: 138836-01-8
• Molecular Formula: C8H10N2O
• Molecular Weight: 150.18
• Mol File: 138836-01-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Cyclopropanol, 2-methyl-1-pyrazinyl-, cis-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopropanol, 2-methyl-1-pyrazinyl-, cis-(138836-01-8)
• EPA Substance Registry System: Cyclopropanol, 2-methyl-1-pyrazinyl-, cis-(138836-01-8)

Safety Data

• Hazardous Substances Data: 138836-01-8(Hazardous Substances Data)

Upstream product

• 61892-81-7 1-(pyrazin-2-yl)butan-1-one 

Relevant articles and documents

Triplet states mediating hydrogen abstraction in 4-acylpyrimidines, 2-acylpyridines, 2-acylpyrazines, and 3-acylpyridazines

Irradiation of 9 leads to hydrogen abstraction by N(1) and fragmentation to 8 from a triplet with ET ～78 kcal/mol. Irradiation of 2-acylpyridines (10) leads to abstraction by both nitrogen and oxygen (cf. eq 4), with the same Stern-Volmer kqτ for the two processes. Irradiation of 2-acylpyrazines (11) can lead to abstraction by either nitrogen (φ27 0.77 from 11b) or oxygen (φ11a 0.95 from 11f)- 3-Acylpyridazine 12d is unreactive on direct irradiation or triplet sensitization with sensitizer ET ～70 kcal/mol; it furnishes a small amount of 12a on sensitization by acetone. Ketone 18 is recovered unchanged from irradiation under all conditions used with 12d. These observations suggest a correlation between the photochemistry of each of these compounds and the energy of the nπ* triplet of the heteroaromatic ring. The nature of the excited state(s) responsible for hydrogen abstraction by nitrogen and oxygen in these ketones is discussed.