138846-93-2Relevant academic research and scientific papers
Conversion of naringenin and hesperetin by heterogeneous catalytic Baeyer-Villiger reaction into lactones exhibiting apoptotic activity
Bernini, Roberta,Mincione, Enrico,Cortese, Manuela,Saladino, Raffaele,Gualandi, Giampiero,Belfiore, Maria Cristina
, p. 4823 - 4825 (2003)
Naringenin and hesperetin were converted into the corresponding lactones by hydrogen peroxide activated by poly(4-vinylpiridine)-supported methyltrioxorhenium in t-butanol, an environmentally friendly catalytic system. The products showed a marked apoptotic activity in the genetic tests.
Benzodiazepine Analogues. Part 11.1 a Kinetic-Mechanistic Study of the Formation of 1,5-Benzodioxepin-2-ones via Baeyer-Villiger Oxidation of Flavanones
Gelebe, Aifheli C.,Kaye, Perry T.
, p. 26 - 27 (2007/10/03)
The regioselective Baeyer-Villiger rearrangement of selected flavanones to 1,5-benzodioxepin-2-ones, using m-chloroperbenzoic acid in CD2Cl2, has been monitored by 1H NMR spectroscopy: substituent effects on the magnitude of the second-order rate constant and the regioselectivity of heteroatom insertion have been examined.
Synthesis and structure of 3,4-dihydro-4-phenyl-1,5-benzodioxepin-2-ones
Gelebe,Kaye,Lidell
, p. 2263 - 2268 (2007/10/02)
Baeyer-Villiger rearrangement of substituted flavanones using MCPBA affords ring-expanded products, shown by NMR spectroscopy to be the corresponding 3,4-dihydro-4-phenyl-1,5-benzodioxepin-2-ones.
