138846-95-4Relevant academic research and scientific papers
Benzodiazepine Analogues. Part 11.1 a Kinetic-Mechanistic Study of the Formation of 1,5-Benzodioxepin-2-ones via Baeyer-Villiger Oxidation of Flavanones
Gelebe, Aifheli C.,Kaye, Perry T.
, p. 26 - 27 (2007/10/03)
The regioselective Baeyer-Villiger rearrangement of selected flavanones to 1,5-benzodioxepin-2-ones, using m-chloroperbenzoic acid in CD2Cl2, has been monitored by 1H NMR spectroscopy: substituent effects on the magnitude of the second-order rate constant and the regioselectivity of heteroatom insertion have been examined.
Synthesis and structure of 3,4-dihydro-4-phenyl-1,5-benzodioxepin-2-ones
Gelebe,Kaye,Lidell
, p. 2263 - 2268 (2007/10/02)
Baeyer-Villiger rearrangement of substituted flavanones using MCPBA affords ring-expanded products, shown by NMR spectroscopy to be the corresponding 3,4-dihydro-4-phenyl-1,5-benzodioxepin-2-ones.
