138852-39-8Relevant articles and documents
New (Ether-Phosphine) Ligands with Different Electronic and Steric Properties
Lindner, Ekkehard,Dettinger, Johannes,Moeckel, Andrea
, p. 1519 - 1524 (2007/10/02)
New ether-phosphines of the type Ph2P-D (2d, 2g-l, 2n-p) with different electronic and steric properties which are provided with open-chained or cyclic ether moieties are obtained by reaction of LiPPh2 with the corresponding chloromethyl substituted ethers ClCH2-D (1d, 1g-l, 1n-p) in THF.The ligands 2d, 2g-l, and 2n-p are characterized by selected IR and NMR data which function as probes for complexation to transition metals.Ether-Phosphines, O-Basicity, Stereochemistry