138857-33-7

Basic information

• Product Name: 3-Decen-2-ol, 4-methyl-, (Z)-
• CAS NO: 138857-33-7
• Molecular Formula: C11H22O
• Molecular Weight: 170.295
• Mol File: 138857-33-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Decen-2-ol, 4-methyl-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Decen-2-ol, 4-methyl-, (Z)-(138857-33-7)
• EPA Substance Registry System: 3-Decen-2-ol, 4-methyl-, (Z)-(138857-33-7)

Safety Data

• Hazardous Substances Data: 138857-33-7(Hazardous Substances Data)

Upstream product

• 917-54-4 methyllithium 
• 138857-31-5 1-Brom-3-(1-bromethenyl)benzol 

Relevant articles and documents

Alkyliron and Alkylcobalt Reagents, IV.- High Superiority of Me4CoLi2 and Me4FeLi2 in Comparison to Me2CuLi and Me4MnLi2 in Cross Coupling Reactions with Vinyl Bromides

The complexes Me4MLi2 (M = Co, Fe, Mn) and Me2CuLi (prepared in situ, but well-known in isolated form) were treated with a series of vinyl bromides.In nearly all cases Me4CoLi2 and Me4FeLi2 proved to by far the best methylating reagents (high yields, reaction at -78 deg C, short reaction time, no excess of the reagent necessary.These reagents will tolerate a hydroxy or cyano group in the substrate, whereas the classical reagent for methylation of vinyl bromides, Me2CuLi, is strongly inhibited by these groups.With the methylation of hydroxyvinyl bromides a new method was found for the synthesis of allyl alcohols. Key Words: Organocobalt complexes / Organoiron complexes