1388770-53-3Relevant academic research and scientific papers
Aluminium triflate catalysed O-glycosidation: Temperature-switched selective Ferrier rearrangement or direct addition with alcohols
Williams, D. Bradley G.,Simelane, Sandile B.,Kinfe, Henok H.
supporting information; experimental part, p. 5636 - 5642 (2012/08/07)
A temperature-controlled mechanism switch between the Al(OTf) 3-catalysed direct addition of alcohols or the Ferrier rearrangement reactions in some glycals is presented. The scope and limitations are investigated as are the influence of the st
Direct Ferrier rearrangement on unactivated glycals catalyzed by indium(III) chloride
Nagaraj, Paramathevar,Ramesh, Namakkal G.
supporting information; experimental part, p. 3970 - 3973 (2009/10/04)
Anhydrous InCl3 has been shown to efficiently catalyze the Ferrier rearrangement by a direct allylic substitution of the hydroxyl group at C-3 position of glycals to afford the corresponding 2,3-unsaturated glycosides in high yields at ambient
