138920-51-1

Basic information

• Product Name: Molybdenum, bis(acetonitrile)dicarbonylchloro(trichlorogermyl)(triphenylphosphine)-
• CAS NO: 138920-51-1
• Molecular Formula: C24H21Cl4GeMoN2O2P
• Molecular Weight: 710.759
• Mol File: 138920-51-1.mol

Chemical Properties

• CAS DataBase Reference: Molybdenum, bis(acetonitrile)dicarbonylchloro(trichlorogermyl)(triphenylphosphine)-(CAS DataBase Reference)
• NIST Chemistry Reference: Molybdenum, bis(acetonitrile)dicarbonylchloro(trichlorogermyl)(triphenylphosphine)-(138920-51-1)
• EPA Substance Registry System: Molybdenum, bis(acetonitrile)dicarbonylchloro(trichlorogermyl)(triphenylphosphine)-(138920-51-1)

Safety Data

• Hazardous Substances Data: 138920-51-1(Hazardous Substances Data)

Upstream product

• 306763-77-9 MoCl(GeCl₃)(CO)3(NCCH₃)2 

Downstream Products

• 155350-96-2 {chloro(GeCl₃)(carbonyl)2(acetonitrile)(PPh₃)(SbPh₃)molybdenum(II)} 
• 155350-73-5 {chloro(GeCl₃)(carbonyl)2(acetonitrile)(PPh₃)2molybdenum(II)} 
• 148800-50-4 {MoCl(GeCl₃)(CO)(NCCH₃)(P(C₆H₅)3)(C₆H₅C₂C₆H₅)} 
• 139604-48-1 molybdenum(II)Cl(GeCl3)(CO)(NCme)(PPh3)(η2-but-2-yne) 

Relevant articles and documents

The synthesis and reactions with neutral monodentate ligands of the seven-coordinate complex

The reaction of fac- (prepared in situ) with an equimolar quantity of GeCl4 rapidly affords the molybdenum(II) seven-coordinate complex (1) in quantitative yield.Equimolar quantities of 1 and L (L=PPh3, AsPh3 or SbPh3) react in CH2Cl2 or NCMe to give or , respectively.The reactions of and with a series of neutral and anionic donor ligands are described.Complex 1 reacts with two equivalents of L (L=PPh3, AsPh3, SbPh3 or PPh2Cy) in CH2Cl2 to afford and .Reactions of are also discussed.Key words: Molybdenum; Acetonitrile; Germanium; Monodentate