1389393-10-5

Basic information

• Product Name: C₄₆H₅₄CsF₆NO₁₂S₂
• Synonyms: C₄₆H₅₄CsF₆NO₁₂S₂
• CAS NO: 1389393-10-5
• Molecular Weight: 1123.96
• Mol File: 1389393-10-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₄₆H₅₄CsF₆NO₁₂S₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₄₆H₅₄CsF₆NO₁₂S₂(1389393-10-5)
• EPA Substance Registry System: C₄₆H₅₄CsF₆NO₁₂S₂(1389393-10-5)

Safety Data

• Hazardous Substances Data: 1389393-10-5(Hazardous Substances Data)

Upstream product

• 161282-96-8 25,27-bis(2-propyloxy)calix<4>arene-crown-6 
• 178631-04-4 1-octyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide 

Relevant articles and documents

Crystallization of cesium complex containing bis(2-propyloxy)calix[4]crown- 6 and bis[(trifluoromethyl)sulfonyl]imide

A complex of Cs+ with the calixcrown bis(2-propyloxy)calix[4] crown-6 (BPC6) and bis[(trifluoromethyl)sulfonyl]imide (NTf2 -), an anion of ionic liquid (IL), was crystallized in the interface region between n-octanol and water. The compound was characterized by single crystal X-ray diffraction, ESI-MS, FT-IR, TGA and PXRD. Cs+ is coordinated with BPC6 by both the six oxygen atoms of the crown and the cation-π interactions, and with the anion NTf2- via one oxygen atom of the sulfonyl group. This single crystal explains the good extraction ability of BPC6 to Cs+ and reflects a coordinating interaction of NTf2- with the deficient complex [Cs·BPC6]+ during the extraction with an IL as diluent.