13894-14-9

Upstream product

• 2396-68-1 4-t-butylbenzenethiol 

Downstream Products

• 57371-69-4 N-(4-tert-Butyl-phenylsulfanyl)-N'-(4-chloro-2-methyl-phenyl)-N-methyl-formamidine 
• 57371-86-5 C₂₀H₂₆N₂S 
• 74880-50-5 (1R,4S,5S,6S)-5-(4-tert-Butyl-phenylsulfanyl)-6-chloro-bicyclo[2.2.1]hept-2-ene 
• 66637-49-8 N-Methyl-N-[4-(tert-butyl)phenylsulfenyl]carbamoyl fluoride 
• 85609-03-6 phenyl p-(tert-butyl)phenyl sulfide 
• 50539-70-3 2,3-Dihydro-2,2-dimethyl-7-benzofuranyl (4-tert-butylphenylthio)(methyl)carbamate 
• 62838-84-0 4,4'-Di-t-butyldibenzolsulfenamid 
• 74880-30-1 (1S,2S,3R,4R,6R)-3-(4-tert-Butyl-phenylsulfanyl)-1-chloromethyl-tricyclo[2.2.1.0^2,6]heptane 
• 52145-37-6 Methyl-carbamic acid 4-(4-tert-butyl-phenylsulfanyl)-2,5-dimethyl-phenyl ester 
• 57372-05-1 N'-(3,5-Bis-trifluoromethyl-phenyl)-N-(4-tert-butyl-phenylsulfanyl)-N-methyl-formamidine 

Relevant academic research and scientific papers

Formation of α-chalcogenyl acrylamides through unprecedented chalcogen-mediated metal-free oxyfunctionalization of ynamides with DMSO as an oxidant

A novel chalcogen-mediated oxyfunctionalization mode of ynamides for the synthesis of α-chalcogenyl acrylamides has been developed. Independent of metal catalysts, external oxidants and additives, this mild process afforded a range of structurally diverse

Trichloroisocyanuric acid-promoted thiolation of phosphites by thiols

A simple and convenient method for the synthesis of thiophosphates by coupling of phosphites with thiols under mild conditions has been developed. The reactions were promoted by trichloroisocyanuric acid (TCCA) and were carried out at room temperature in

Generation of Oxazolidine-2,4-diones Bearing Sulfur-Substituted Quaternary Carbon Atoms by Oxothiolation/Cyclization of Ynamides

A novel method for metal-free oxothiolation of ynamides to construct oxazolidine-2,4-diones bearing sulfur-substituted quaternary carbon atoms has been developed. It represents a rare C-O bond cleavage of ynamides, as well as a facile and tandem approach for the formation of C-O, C-S, and C-Cl bonds. This redox-neutral protocol can be applied to the synthesis of multisubstituted oxazolidine-2,4-diones with good chemoselectivity and good yields of isolated products under mild conditions.

Synthesis of aryl thioethers through the N -chlorosuccinimide-promoted cross-coupling reaction of thiols with Grignard reagents

A convenient one-pot approach for the synthesis of aryl sulfides through the coupling of thiols with Grignard reagents in the presence of N-chlorosuccinimide is described. The sulfenylchlorides were formed when thiols were treated with N-chlorosuccinimide, and the resulting sulfenylchlorides were then directly reacted with Grignard reagents to provide aryl sulfides in good to excellent yields under mild reaction conditions. Functional groups including ester, fluoro, and chloro are tolerated by the reaction conditions employed. It is important to note that this method has a short reaction time (30 min in total) and represents an alternative approach for the synthesis of aryl sulfides over the existing protocols.

N-[4-(Tert-butyl)phenylsulfenyl]-N-alkylcarbamoyl fluoride compounds

N-[4-(tert-butyl)phenylsulfenyl]-N-alkylcarbamoyl fluoride compounds are useful as intermediates in the preparation of pesticidally active carbamoyloxime compounds.