138956-44-2Relevant academic research and scientific papers
TiCl4-Mediated Reactions of Alkyl Azides with Cyclic Ketones
Aube, Jeffrey,Milligan, Gregory L.,Mossman, Craig J.
, p. 1635 - 1637 (1992)
The reaction of cyclic ketones with alkyl azides to afford N-alkyl lactams can be effected by TiCl4.
Reactions of alkyl azides and ketones as mediated by Lewis acids: Schmidt and Mannich reactions using azide precursors
Desai, Pankaj,Schildknegt, Klaas,Agrios, Konstantinos A.,Mossman, Craig,Milligan, Gregory L.,Aube, Jeffrey
, p. 7226 - 7232 (2007/10/03)
The Lewis acid-promoted reactions of alkyl azides with ketones can afford several products. Chief among these result from a Schmidt-like insertion of the azide into the carbon - carbon bond adjacent to the carbonyl group. Alternatively, an acid-promoted r
