13896-15-6Relevant academic research and scientific papers
Structure and properties of a sulfur(IV)-sulfur(II)-bond compound: Reversible conversion of a sulfur-substituted organosulfurane into a thiol
Kano, Naokazu,Itoh, Yusuke,Watanabe, Yuki,Kusaka, Shinpei,Kawashima, Takayuki
supporting information; experimental part, p. 9430 - 9433 (2009/05/06)
(Figure Presented) A highly polar hypervalent SIV - S II bond was formed in the synthesis of a sulfur-substituted sulfurane (see scheme), which was crystallographically characterized. Reduction of the 1,2-dithietane gives the corresp
NEW THIOCARBONYL YLIDES FROM THIOBENZOPHENONE
Huisgen, Rolf,Xingya, Li
, p. 2363 - 2368 (2007/10/02)
Thiobenzophenone is converted to 1,3,4-thiadiazolines by reaction with diazoethane, phenyldiazomethane or diphenyldiazomethane at -78 deg C.Extrusion of nitrogen from the thiadiazolines furnishes thiocarbonyl ylides which, in turn, undergo electrocyclic r
