138963-22-1Relevant academic research and scientific papers
Glycosylidene carbenes: Part 32: Reaction of glycosylidene diaziridines with acylating and sulfonylating agents
Mangholz, Sissi E.,Briner, Karin,Bernet, Bruno,Vasella, Andrea
, p. 2490 - 2508 (2007/10/03)
Acylation and sulfonylation of the N,N'-unsubstituted glucosylidenespirodiaziridines 1A/1B 95:5 with Ac2O, BzCl, FmocCl, TsCl, (naphthalen-2-yl)sulfonyl, and (2,4,6-triisopropylphenyl)sulfonyl chloride, and concomitant rearrangement gave the ac
Glycosylidene Carbenes Part 5 Synthesis of Glycono-1,5-lactone Tosylhydrazones as Precursors of Glycosylidene Carbenes
Mangholz, Sissi E.,Vasella, Andrea
, p. 2100 - 2111 (2007/10/02)
The benzyl- and the acyl-protected glyconolactone tosylhydrazones 6, 9, 12, 16, and 19 (Scheme 1) were prepared in good yields by treating the hemiacetals 4, 7, 10, 14, and 17 with N-tosylhydrazine, to give the N-glycosylhydrazines 5, 8, 11, 15, and 18, a
