138964-05-3Relevant academic research and scientific papers
The First Synthesis of Aliphatic Sulfines from Thiono-esters
Lemarie, Margareth,Pham, Thi-Nhan,Metzner, Patrick
, p. 7411 - 7414 (1991)
Reaction of various thiono-esters with one equivalent of meta-chloroperoxybenzoic acid at 0 deg C in dichloromethane furnishes the corresponding sulfines, evidenced for the first time.These thiocarbonyl oxides are rather unstable at room temperature and give carboxylic esters, with loss of sulfur.The overall sequence provides an easy and quantitative C=S -> C=O transformation.
