138996-81-3

Basic information

• Product Name: Phosphine, bis(4-methoxyphenyl)-1-naphthalenyl-
• CAS NO: 138996-81-3
• Molecular Formula: C24H21O2P
• Molecular Weight: 372.403
• Mol File: 138996-81-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Phosphine, bis(4-methoxyphenyl)-1-naphthalenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphine, bis(4-methoxyphenyl)-1-naphthalenyl-(138996-81-3)
• EPA Substance Registry System: Phosphine, bis(4-methoxyphenyl)-1-naphthalenyl-(138996-81-3)

Safety Data

• Hazardous Substances Data: 138996-81-3(Hazardous Substances Data)

Upstream product

• 90-14-2 1-Iodonaphthalene 
• 84127-04-8 bis(4-methoxyphenyl)phosphine 
• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 15754-51-5 bis(4-methoxyphenyl)phosphine oxide 
• 90-11-9 1-Bromonaphthalene 

Downstream Products

• 138996-95-9 1-[Bis-(4-methoxy-phenyl)-phosphinothioyl]-1,4-dihydro-naphthalene 
• 138996-86-8 (3,4-dihydro-1-naphthyl)bis(4-methoxyphenyl)phosphine 
• 138996-85-7 (1,4-dihydro-1-naphthyl)bis(4-methoxyphenyl)phosphine 
• 141868-60-2 3-propanoic acid 

Relevant articles and documents

Copper-catalyzed C–P cross-coupling of secondary phosphines with (hetero)aromatic bromide

A novel and convenient approach to the synthesis of various tertiary phosphines via a copper-catalyzed cross-coupling of (hetero)aromatic bromide with secondary phosphines has been developed. The reaction employs cheap copper as the catalyst, 2,6-bis(N-methylaminomethyl)pyridine (L4) as a perfect ligand and KOtBu as a base; all reactions are carried out under argon atmosphere. A variety of sterically hindered and/or functionalized substrates were found to react under these reaction conditions to provide products in good to excellent yields. Moreover, ten new tertiary phosphines were first reported in this process.