139014-89-4Relevant academic research and scientific papers
Intramolecular trapping of difluoroalkyl radicals by tethered olefin in the asymmetric synthesis of 2,4-disubstituted-3,3-difluorotetrahydrofurans
Cavicchio, Giancarlo,Marchetti, Valeria,Arnone, Alberto,Bravo, Pierfrancesco,Viani, Fiorenza
, p. 9439 - 9448 (2007/10/02)
Optically pure propenyl ethers of 3-sulphenyl-, 3-sulphuryl-, and 3-sulphonyl-1-chloro-1,1-difluoropropan-2-ols were submitted to radical cyclization affording, with moderate to high diastereoselectivity. 3,3-difluorotetrahydrofurans containing in 2 and 4
