139016-29-8Relevant articles and documents
Copper(I)-Catalyzed Enantioselective Addition of Enynes to Ketones
Wei, Xiao-Feng,Xie, Xiao-Wei,Shimizu, Yohei,Kanai, Motomu
, p. 4647 - 4650 (2017)
A copper(I)-catalyzed enantioselective addition of enynes to ketones was developed. The method allows facile construction of enantiomerically enriched tertiary alcohols using skipped enynes as stable hydrocarbon pronucleophiles. The combination of a soft
Catalytic Regio- and Enantioselective Proton Migration from Skipped Enynes to Allenes
Wei, Xiao-Feng,Wakaki, Takayuki,Itoh, Taisuke,Li, Hong-Liang,Yoshimura, Takayoshi,Miyazaki, Aya,Oisaki, Kounosuke,Hatanaka, Miho,Shimizu, Yohei,Kanai, Motomu
supporting information, p. 585 - 599 (2019/03/11)
Chiral allenes are highly valuable as versatile synthetic intermediates and core skeletons of various functional organic molecules. Despite marked recent advances, the straightforward catalytic enantioselective synthesis of hydrocarbon allenes from readil