139058-71-2Relevant academic research and scientific papers
Additive Pummerer reactions of vinylic sulphoxides. Synthesis of 2-(phenylsulphenyl) aldehydes and primary alcohols
Craig,Daniels,MacKenzie
, p. 6973 - 6976 (1991)
Reaction in acetic anhydride solution of α,β-unsaturated sulphoxides 1 with sodium acetate and triflic anhydride gives 2-(phenylsulphenyl) acylals 4. Basic methanolysis of 4 gives 2-(phenylsulphenyl) aldehydes 8, whilst reduction gives directly 2-(phenylsulphenyl) primary alcohols 9.
