13910-17-3Relevant academic research and scientific papers
Facile Thiol–Ene Click Protocol Using Benzil as Sensitizer and White LED as Light Source
Das, Anupam,Thomas, K. R. Justin
supporting information, p. 7214 - 7218 (2020/11/30)
The thiol–ene reaction leading to a series of thioether derivatives by simple metal and oxidant free visible light promoted photosensitized protocol, following anti-Markonikov hydrothiolation of unactivated aryl and alkyl olefins at room temperature is demonstrated. Benzil served as a green photosensitizer in this reaction and white LED lights as a light source. This radical based thiol–ene reaction is operationally simple and tolerates a wide variety of functional groups present in olefins.
One-pot synthesis of symmetrical and unsymmetrical aryl sulfides by Pd-catalyzed couplings of aryl halides and thioacetates
Park, Namjin,Park, Kyungho,Jang, Mihee,Lee, Sunwoo
experimental part, p. 4371 - 4378 (2011/07/06)
Aryl sulfides were obtained from the coupling reaction of S-aryl (or S-alkyl) thioacetates and aryl bromides in the presence of palladium catalyst. This reaction method enables the one-pot synthesis of symmetrical and unsymmetrical diaryl sulfides by employing potassium thioacetate with aryl iodides and aryl bromides.
