139101-19-2

Basic information

• Product Name: Butanoic acid, 2-fluoro-3-oxo-, phenylMethyl ester
• Synonyms: Butanoic acid, 2-fluoro-3-oxo-, phenylMethyl ester
• CAS NO: 139101-19-2
• Molecular Formula: C₁₁H₁₁FO₃
• Molecular Weight: 210.2016432
• Mol File: 139101-19-2.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Butanoic acid, 2-fluoro-3-oxo-, phenylMethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Butanoic acid, 2-fluoro-3-oxo-, phenylMethyl ester(139101-19-2)
• EPA Substance Registry System: Butanoic acid, 2-fluoro-3-oxo-, phenylMethyl ester(139101-19-2)

Safety Data

• Hazardous Substances Data: 139101-19-2(Hazardous Substances Data)

Upstream product

• 5396-89-4 benzyl acetoacetate 

Downstream Products

• 1192024-61-5 (S)-benzyl 2-((S)-(tert-butoxycarbonylamino)(p-tolyl)-methyl)-2-fluoro-3-oxobutanoate 
• 1260109-02-1 ditert-butyl (R)-1-(1-(benzyloxy)-2-fluoro-1,3-dioxobutan-2-yl)hydrazine-1,2-dicarboxylate 
• 139101-22-7 benzyl 2-bromo-2-fluoro-3-oxobutyrate 

Relevant articles and documents

One-pot synthesis of 3,5-disubstituted and polysubstituted phenols from acyclic precursors

A new strategy for the synthesis of 3,5-disubstituted phenols is established through one-pot Robinson annulation of α,β-unsaturated ketones with α-fluoro-β-ketoesters followed by in situ dehydrofluorination and tautomerization. This method has been extended to the synthesis of polysubstituted phenols and applied in the preparation of biologically active compounds.

Chemistry of Novel Compounds with Multifunctional Carbon Structure. 7. Synthetic Studies of the Potentially Versatile Monofluoro Molecules, α-Functionalized α-Fluoro-β-keto Esters

-