139139-81-4

Basic information

• Product Name: Bis(4-bromophenyl)iodonium trifluoromethanesulfonate
• Synonyms: (p-Br-Ph)2IOTf;Bis(4-bromophenyl)iodonium trifluoromethanesulfonate
• CAS NO: 139139-81-4
• Molecular Formula: CF₃O₃S*C₁₂H₈Br₂I
• Molecular Weight: 587.9734996
• Mol File: 139139-81-4.mol
• Article Data: 35

Chemical Properties

• Melting Point: 212 °C
• Appearance: /
• Solubility: soluble in Methanol
• BRN: 4900069
• CAS DataBase Reference: Bis(4-bromophenyl)iodonium trifluoromethanesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: Bis(4-bromophenyl)iodonium trifluoromethanesulfonate(139139-81-4)
• EPA Substance Registry System: Bis(4-bromophenyl)iodonium trifluoromethanesulfonate(139139-81-4)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26
• WGK Germany: 3
• Hazardous Substances Data: 139139-81-4(Hazardous Substances Data)

Upstream product

• 1493-13-6 trifluorormethanesulfonic acid 
• 5467-74-3 4-Bromophenylboronic acid 
• 41018-52-4 (4-bromophenyl)-λ³-iodanediyl diacetate 
• 589-87-7 1,4-bromoiodobenzene 
• 35895-70-6 tetrabutylammonium trifluoromethylsulfonate 
• 109-63-7 boron trifluoride diethyl etherate 
• 108-86-1 bromobenzene 
• 358-23-6 trifluoromethylsulfonic anhydride 
• 6999-03-7 1-bromo-4-(trimethylsilyl)benzene 
• 58735-50-5 iodosyl trifluoromethanesulfonate 

Downstream Products

• 1265678-95-2 4-bromophenyl dodecanoate 
• 1523-17-7 4-bromophenyl benzoate 
• 35895-70-6 tetrabutylammonium trifluoromethylsulfonate 
• 22772-25-4 5-bromo-2-(4-methylphenyl)benzofuran 
• 65440-82-6 O-(4-bromophenyl)hydroxylamine 

Relevant articles and documents

Novel λ3-Iodane-Based Functionalization of Synthetic Carbon Allotropes (SCAs) - Common Concepts and Quantification of the Degree of Addition

The covalent functionalization of carbon allotropes represents a main topic in the growing field of nano materials. However, the development of functional architectures is impeded by the intrinsic polydispersibility of the respective starting material, th

Multicomponent Synthesis of Biologically Relevant S-Aryl Dithiocarbamates Using Diaryliodonium Salts

A transition-metal-free one-pot three-component annulation between diaryliodonium triflates, cyclic and acyclic aliphatic amines, and carbon disulfide providing a convenient and efficient access to biologically relevant S-aryl dithiocarbamates is developed. The reaction does not require metal, base, or any other additive and operates under mild and ambient conditions. This methodology is robust, scalable, and exhibits a broad substrate scope. The in silico analysis revealed that the majority of the compounds have a drug-likeness and good ADMET characteristics.

Versatile and base-free copper-catalyzed α-arylations of aromatic ketones using diaryliodonium salts

A ligand and base-free copper catalyzed synthetic method for the efficient α-arylation of aromatic ketones is described. In order to avoid strong bases, ketone-derived silyl enol ethers were employed. Their reaction with diaryliodonium salts as aryl source provided the intermolecular C–C coupling displaying good functional group tolerance and requiring low catalyst loading.

Direct Copper-Catalyzed C-3 Arylation of Diphenylphosphine Oxide Indoles

We have developed a simple and effective method for the C-3 arylation of phosphorus-containing indole compounds in the presence of CuI under mild conditions. This reaction provides a reliable method for the modification of ligands.