1391524-23-4

Basic information

• Product Name: 2,5-di(1-H-pyrazol-4-yl)benzenesulfonic acid
• CAS NO: 1391524-23-4
• Molecular Weight: 290.302
• Mol File: 1391524-23-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,5-di(1-H-pyrazol-4-yl)benzenesulfonic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-di(1-H-pyrazol-4-yl)benzenesulfonic acid(1391524-23-4)
• EPA Substance Registry System: 2,5-di(1-H-pyrazol-4-yl)benzenesulfonic acid(1391524-23-4)

Safety Data

• Hazardous Substances Data: 1391524-23-4(Hazardous Substances Data)

Upstream product

• 1036248-62-0 4,4'-benzene-1,4-diylbis(1H-pyrazole) 

Relevant articles and documents

Tuning the adsorption properties of isoreticular pyrazolate-based metal-organic frameworks through ligand modification

Two isoreticular series of pyrazolate-based 3D open metal-organic frameworks, MBDP-X, adopting the NiBDP and ZnBDP structure types [H 2BDP = 1,4-bis(1H-pyrazol-4-yl)benzene], were synthesized with the new tagged organic linkers H2BDP-X (X = -NO2, -NH 2, -OH). All of the MBDP-X materials have been characterized through a combination of techniques. IR spectroscopy proved the effective presence of tags, while X-ray powder diffraction (XRPD) witnessed their isoreticular nature. Simultaneous TG/DSC analyses (STA) demonstrated their remarkable thermal stability, while variable-temperature XRPD experiments highlighted their high degree of flexibility related to guest-induced fit processes of the solvent molecules included in the channels. A structural isomer of the parent NiBDP was obtained with a sulfonate tagged ligand, H2BDP-SO3H. Structure solution from powder diffraction data collected at three different temperatures (room temperature, 90, and 250 °C) allowed the determination of its structure and the comprehension of its solvent-related flexible behavior. Finally, the potential application of the tagged MOFs in selective adsorption processes for gas separation and purification purposes was investigated by conventional single component adsorption isotherms, as well as by advanced experiments of pulse gas chromatography and breakthrough curve measurements. Noteworthy, the results show that functionalization does not improve the adsorption selectivity (partition coefficients) for the resolution of gas mixtures characterized by similar high quadrupole moments (e.g., CO 2/C2H2); however, the resolution of gas mixtures containing molecules with highly differentiated polarities (i.e., N2/CO2 or CH4/CO2) is highly improved.