139177-23-4

Basic information

• Product Name: Benzenemethanol, 2-(4,5-dihydro-4,4-dimethyl-2-oxazolyl)-6-methoxy-
• CAS NO: 139177-23-4
• Molecular Formula: C13H17NO3
• Molecular Weight: 235.283
• Mol File: 139177-23-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, 2-(4,5-dihydro-4,4-dimethyl-2-oxazolyl)-6-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 2-(4,5-dihydro-4,4-dimethyl-2-oxazolyl)-6-methoxy-(139177-23-4)
• EPA Substance Registry System: Benzenemethanol, 2-(4,5-dihydro-4,4-dimethyl-2-oxazolyl)-6-methoxy-(139177-23-4)

Safety Data

• Hazardous Substances Data: 139177-23-4(Hazardous Substances Data)

Upstream product

• 50-00-0 formaldehyd 
• 73453-77-7 3-(4,4-dimethyloxazolin 2-yl)anisole 
• 139177-22-3 2-[2-(Allyl-dimethyl-silanylmethyl)-3-methoxy-phenyl]-4,4-dimethyl-4,5-dihydro-oxazole 

Relevant articles and documents

Synthesis of Tertiary Alcohols via the Use of the Allyldimethylsilyl Moiety as a Latent Hydroxyl Group in the Kumada-Fleming-Tamao Reaction

The phenyldimethylsilyl to hydroxyl transformation fails in the cases where a cyclic tertiary carbon center is involved as was observed in the synthesis of phorbol C-ring models.An alternate functionality in the form of allyldimethylsilane (ADMS) is found to work well in these and other cases involving tertiary centers.With proper choice of reagents, the ADMS group can be employed as a latent alcohol in systems containing ketones, esters, arenes, and vinyl groups.