1391853-69-2Relevant articles and documents
An electron-rich molybdenum-molybdenum quintuple bond spanned by one lithium atom
Liu, Shin-Cheng,Ke, Wei-Lun,Yu, Jen-Shiang K.,Kuo, Ting-Shen,Tsai, Yi-Chou
, p. 6394 - 6397 (2012)
Take five: A unique quintuply bonded dimolybdenum complex [Mo 2(μ-Li){μ-HC(N-2,6-Et2C6H 3)2}3] (see picture) was synthesized and characterized. The Mo-Mo interaction includes an unexpected bridging Li + ion. Calculations indicate the bridging Li+ ion does not perturb the Mo-Mo bond length (2.0612(4) A?), but results in a relatively small effective Mo-Mo bond order of 3.67. Copyright