139190-83-3Relevant academic research and scientific papers
Novel glycosidation method using 2,6-anhydro-2-thio sugars for stereocontrolled synthesis of 2,6-dideoxy-α- and -β-glycosides
Toshima, Kazunobu,Mukaiyama, Satsuki,Nozaki, Yuko,Inokuchi, Hatsuki,Nakata, Masaya,Tatsuta, Kuniaki
, p. 9042 - 9051 (2007/10/02)
Powerful and highly stereocontrolled O-glycosidation methods using several kinds of 2,6-anhydro-2-thio sugars as glycosyl donors have been developed for the synthesis of both 2,6-dideoxy-α- and -β-glycosides which frequently occur in biologically importan
Highly stereoselective glycosylation by conformational assistance of glycosyl donor
Toshima, Kazunobu,Nozaki, Yuko,Tatsuta, Kuniaki
, p. 6887 - 6890 (2007/10/02)
Highly α-stereoselective glycosylation of 2-deoxy-D-fucose was achieved by use of the conformational assistance of the rigid glycosyl donor 2. The selectivity of the glycosylation of 2 was much higher than that of 3 which had a normal chair conformation.
