1391996-52-3Relevant academic research and scientific papers
Base-promoted aryl carbon-iodine and carbon-bromine bond cleavage with rhodium porphyrin complexes: Scope and mechanism
Qian, Ying Ying,Chan, Kin Shing
, p. 5452 - 5462 (2012/11/13)
Base-promoted aryl carbon-iodine and carbon-bromine bond (Ar-X, X = I, Br) cleavage by rhodium porphyrin complexes was achieved to give the rhodium(III) porphyrin aryls Rh(ttp)Ar (ttp = tetra-p-tolylporphyrinato dianion). Mechanistic studies showed that RhII2(ttp)2 is the intermediate for Ar-X (X = I, Br) cleavage. The Ar-X cleavage process goes through a rhodium(II) porphyrin radical mediated ipso-substitution mechanism.
