1391998-40-5Relevant academic research and scientific papers
Investigation of the reaction of dithiocarbamic acid salts with aromatic aldehydes
Ziyaei Halimehjani, Azim,Hajiloo Shayegan, Mojtaba,Hashemi, Mohammad Mahmoodi,Notash, Behrooz
supporting information; experimental part, p. 3838 - 3841 (2012/10/08)
A reaction of dithiocarbamic acid salts with carbonyl compounds was investigated for the first time in the presence of BF3?OEt 2. The reaction is temperature dependent and gives gem-bis(dithiocarbamates) at 35-45 °C as a molecule with high equivalents of dithiocarbamate groups. At lower temperatures (15-20 °C), the 2-iminium-1,3-dithietane is obtained as the only product. The structure of a 2-iminium-1,3-dithietane was accomplished by X-ray crystallographic analysis.
