1392015-10-9

Basic information

• Product Name: [RuCl(μ-Cl)(PPh3)(C6H4(PMe2)C(Ph)NH)]2
• CAS NO: 1392015-10-9
• Molecular Weight: 1351.08
• Mol File: 1392015-10-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [RuCl(μ-Cl)(PPh3)(C6H4(PMe2)C(Ph)NH)]2(CAS DataBase Reference)
• NIST Chemistry Reference: [RuCl(μ-Cl)(PPh3)(C6H4(PMe2)C(Ph)NH)]2(1392015-10-9)
• EPA Substance Registry System: [RuCl(μ-Cl)(PPh3)(C6H4(PMe2)C(Ph)NH)]2(1392015-10-9)

Safety Data

• Hazardous Substances Data: 1392015-10-9(Hazardous Substances Data)

Upstream product

• 15529-49-4 tris(triphenylphosphine)ruthenium(II) chloride 
• 33027-76-8 <(Diphenylmethyliden)amino>dimethylphosphin 

Relevant articles and documents

Rearrangements of phosphinoimines to phosphine-imines in ruthenium chelate complexes

Thermal reaction of 1:1 mixtures of the RuCl2(PPh 3)3 and phosphinoimine R2PNCPh2 (R = Ph, iPr, Me) at 140 °C results in isolation of the dimeric species [RuCl(μ-Cl)(PPh3)(C6H4(PPh 2)C(Ph)NH)]2 (R = Ph 1, iPr 2, Me 3) containing phosphine-imine chelating ligands. Subsequent reaction of 1 and 3 with one equivalent of pyridine at room temperature give RuCl2(PPh 3)(py)(C6H4(PR2)C(Ph)NH) (R = Ph 4, Me 5). Excess pyridine reacts with 2 to give a mixture of the cis and trans-isomers of RuCl2(py)2(C6H 4(PiPr2)C(Ph)NH) 6 and 7 respectively. Treatment of 5 with excess PPh3 affords RuCl2(PPh3) 2(C6H4(PMe2)C(Ph)NH) 8. Aspects of the mechanism of the thermal rearrangements of the phosphinoimine to the phosphine-imine ligands are considered and the isolation of RuCl 2(Ph2PNCPh2)(SIMes)(CHPh) 9 and RuCl 2(PPh3)2(HNC(Ph)C6H4) 10 provide support for a proposed mechanism involving a intermediate containing a Ru-bound metallated aryl-imine fragment.