139212-83-2

Upstream product

• 604-69-3 β-D-glucose pentaacetate 
• 1005-56-7 phenylcarbonochloridothioate 
• 139212-80-9 1,2,3,6-Tetra-O-acetyl-4-O-phenoxythiocarbonyl-α-D-idopyranose 
• 18977-21-4 1,2,3,6-tetra-O-acetyl-α-D-idopyranose 

Downstream Products

• 139212-85-4 (2S,3R,4R,5S,6R)-2,4-Diacetoxy-6-acetoxymethyl-3-bromo-5-phenoxythiocarbonyloxytetrahydropyran 
• 139212-84-3 (2R,3S,4R,5S,6R)-2,4-Diacetoxy-6-acetoxymethyl-3-bromo-5-phenoxythiocarbonyloxytetrahydropyran 

Relevant academic research and scientific papers

Conversion of D-glucose into the β-hydroxy-δ-lactone moiety of mevinic acids and congeners via D-idose as a key chiral intermediate

(4R,6S)-4-Hydroxy-6-hydroxymethyl-3,4,5,6-tetrahydro-2H-pyran-2-one (1) and (4R,6S)-4-hydroxy-6-hydroxymethyl-2-methoxytetrahydropyran (2), chirons of the β-hydroxy-δ-lactone moiety of mevinic acids and congeners, were derived from 1,2,3,6-tetra-O-acetyl-