139219-53-7Relevant academic research and scientific papers
Preparation and some properties of chiral ansa-mono(η5-fluorenyl)zirconium(IV) complexes
Rieger, Bernhard
, p. C17 - C20 (2007/10/02)
Symmetrically-substituted epoxides react with fluorenyllithium to give the corresponding alcohols in high yields.These were used to prepare ansa-bridged mono(η5-fluorenyl)-zirconium complexes of the general formula ZrCl2(thf)2 (CHR-CHR=cyclohexyl, cyclopentyl, 1,2-diphenylethyl).With Al(CH3)3 as cocatalyst these complexes catalyze the polymerization of ethene.
