139219-84-4

Upstream product

• 513-81-5 2,3-dimethyl-buta-1,3-diene 
• 157736-05-5 C₉H₁₃BrClNSSi 
• 615-36-1 2-bromoaniline 
• 61937-72-2 N-trimethylsilyl-ortho-bromoaniline 
• 139219-77-5 N-(2-bromophenylaminosulfanyl)phthalimide 

Relevant academic research and scientific papers

Metal-assisted fragmentation of N-aryl- and -alkyl-N-trimethylsilylaminosulfur chlorides and N-aryl- and -alkyl-aminosulfur chlorides in the presence of conjugated dienes: Synthesis and reactivity of 2-substituted-3,6-dihydro-1,2-thiazines

N-Alkyl- and -aryl-N-trimethylsilylaminosulfur chlorides 2 and N-aryl- and -alkyl-aminosulfur chlorides 8 fragment in the presence of silver ions and a conjugated diene to yield 2-substituted-3,6-dihydro-1,2-thiarines 6 as the major products, possibly via

Alkylthionitroso and arylthionitroso compounds generated from N- trimethylsilyl-N-chlorothioalkylamine precursors

A range of alkylthionitroso and arylthionitroso compounds have been generated by thermal fragmentation of N-trimethylsilyl-N- chlorothioalkyl(aryl)amine precursors, and intercepted by reaction with dimethylbutadiene to afford Diels-Alder and ene adducts.

Diels-Alder and Ene Reactions of New Transient Thionitrosoarenes (Ar-N=S) and Thionitrosoheteroarenes (Het-N=S) Generated from N-(Arylaminosulfanyl)- and N-(Heteroarylaminosulfanyl)-phthalimides: Synthesis of Cyclic and Acyclic Sulfenamides

A series of new N-(arylaminosulfanyl)- and N-(heteroarylaminosulfanyl)-phthalimide derivatives 3i-m and 3o-r, has been prepared by reaction of chlorosulfanylphthalimide with the trimethylsilyl derivative of the appropriate arylamine or heteroarylamine.On

Generation and trapping of ortho-substituted thionitrosobenzenes: Competitive Diels-Alder and ene reactions with dimethylbutadiene

Transient thionitrosoarenes, ArN=S, (2) that bear a substituent (CN, Br or Me) ortho to the reactive N=S group have been generated by two entirely different routes and intercepted with dimethylbutadiene to afford mixtures of Diels-Alder and ene adducts, (