1392201-54-5Relevant articles and documents
Cross-trienamines in asymmetric organocatalysis
Halskov, Kim Soholm,Johansen, Tore Kiilerich,Davis, Rebecca L.,Steurer, Marianne,Jensen, Frank,Jorgensen, Karl Anker
supporting information; experimental part, p. 12943 - 12946 (2012/09/25)
Cross-conjugated trienamines are introduced as a new concept in asymmetric organocatalysis. These intermediates are applied in highly enantioselective Diels-Alder and addition reactions, providing functionalized bicyclo[2.2.2]octane compounds and γ′-addition products, respectively. The nature of the transformations and the intermediates involved are investigated by computational calculations and NMR analysis.