1392229-39-8

Basic information

• Product Name: (4S,5S)-4,5-bis((tert-butyldimethylsilyl)oxy)-3-chlorocyclohex-2-en-1-one
• Synonyms: (4S,5S)-4,5-bis((tert-butyldimethylsilyl)oxy)-3-chlorocyclohex-2-en-1-one
• CAS NO: 1392229-39-8
• Molecular Weight: 391.098
• Mol File: 1392229-39-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4S,5S)-4,5-bis((tert-butyldimethylsilyl)oxy)-3-chlorocyclohex-2-en-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: (4S,5S)-4,5-bis((tert-butyldimethylsilyl)oxy)-3-chlorocyclohex-2-en-1-one(1392229-39-8)
• EPA Substance Registry System: (4S,5S)-4,5-bis((tert-butyldimethylsilyl)oxy)-3-chlorocyclohex-2-en-1-one(1392229-39-8)

Safety Data

• Hazardous Substances Data: 1392229-39-8(Hazardous Substances Data)

Upstream product

• 426206-55-5 {[(1S,2S)-3-chloro-3-cyclohexene-1,2-diyl]bis(oxy)}bis[(1,1-dimethylethyl)dimethylsilane] 
• 176166-15-7 cis-(1S,2S)-1,2-dihydroxy-3-chlorocyclohex-3-ene 
• 86992-79-2 (1S,2S)-3-Chloro-cyclohexa-3,5-diene-1,2-diol 

Downstream Products

• 1392229-29-6 (4S,5S)-3-chloro-4,5-dihydroxycyclohex-2-enone 

Relevant articles and documents

Structure, stereochemistry and synthesis of enantiopure cyclohexenone cis-diol bacterial metabolites derived from phenols

Biotransformation of 3-substituted and 2,5-disubstituted phenols, using whole cells of P. putida UV4, yielded cyclohexenone cis-diols as single enantiomers; their structures and absolute configurations have been determined by NMR and ECD spectroscopy, X-ray crystallography, and stereochemical correlation involving a four step chemoenzymatic synthesis from the corresponding cis-dihydrodiol metabolites. An active site model has been proposed, to account for the formation of enantiopure cyclohexenone cis-diols with opposite absolute configurations.