1392233-63-4Relevant academic research and scientific papers
Double cyclization/aryl migration across an alkyne bond enabled by organoboryl and diarylplatinum groups
Sun, Christina,Hudson, Zachary M.,Chen, Leanne D.,Wang, Suning
, p. 5671 - 5674 (2012/07/01)
Synergy between metals: Diarylacetylenes 1, containing both a boryl (BMes2) group and a diarylplatinum group, undergo a transformation involving a double metallocyclization/aryl migration to give tetracycles 2 in high diastereoselectivity (see scheme). This remarkable transformation is enabled by the synergistic interplay of the boryl and the diarylplatinum group. Copyright
