1392268-79-9Relevant academic research and scientific papers
Manganese catalysts with C1-symmetric N4 ligand for enantioselective epoxidation of olefins
Wang, Bin,Miao, Chengxia,Wang, Shoufeng,Xia, Chungu,Sun, Wei
, p. 6750 - 6753 (2012/07/03)
Bioinspired manganese complexes based on N4 ligands, with a more rigid, chiral diamine derived from proline and two benzimidazoles, were synthesized and applied to epoxidize olefins with hydrogen peroxide as a clean oxidant. Notably, 60-99 % isolated yields and excellent ee values (up to 95 %) were obtained by using low catalyst loadings (0.01-0.2 mol %; see scheme; F green, S yellow). Copyright
