1392473-01-6Relevant articles and documents
Dicopper(II) metallacyclophanes with electroswitchable polymethyl- substituted para-phenylene spacers
Ferrando-Soria, Jesus,Castellano, Maria,Ruiz-Garcia, Rafael,Cano, Joan,Julve, Miguel,Lloret, Francesc,Ruiz-Perez, Catalina,Pasan, Jorge,Canadillas-Delgado, Laura,Armentano, Donatella,Journaux, Yves,Pardo, Emilio
, p. 12124 - 12137 (2013/09/23)
Double-stranded anionic dinuclear copper(II) metallacyclic complexes of the paracyclophane type [Cu2L2]4- have been prepared by the CuII-mediated self-assembly of different para-phenylenebis(oxamato) bridging li
Redox switching of the antiferromagnetic coupling in permethylated dicopper(ii) paracyclophanes
Ferrando-Soria, Jesus,Castellano, Maria,Ruiz-Garcia, Rafael,Cano, Joan,Julve, Miguel,Lloret, Francesc,Pasan, Jorge,Ruiz-Perez, Catalina,Canadillas-Delgado, Laura,Li, Yangling,Journaux, Yves,Pardo, Emilio
supporting information, p. 8401 - 8403 (2012/10/29)
A unique magnetic electroswitching behavior has been observed in an oxamato-based permethylated dicopper(ii) paracyclophane; upon reversible one-electron oxidation of the double tetramethyl-substituted p-phenylenediamidate bridging skeleton, the spin alignment of the two Cu II ions (SCu = ) changes from antiparallel (OFF) to parallel (ON) in the resulting dicopper(ii) π-radical cation species.