1392495-45-2Relevant academic research and scientific papers
Rhodium-catalyzed three-component reaction between silylacetylene and two ketenes leading to 1,3-enynes bearing a carboxylic ester group via double insertion of ketenes
Ogata, Kenichi,Ohashi, Itsuki,Fukuzawa, Shin-Ichi
supporting information; experimental part, p. 4214 - 4217 (2012/10/08)
The first cross-reaction between a terminal silylacetylene and two ketene molecules leading to 1,3-enynes bearing a carboxylic ester group via double insertion of ketenes is achieved using a cationic rhodium complex catalyst. This reaction is applicable for various symmetrical and unsymmetrical ketenes with good stereoselectivities.
