139278-12-9

Basic information

• Product Name: (4S)-4-benzyl-3-<2-(triphenylphosphonio)acetyl>-2-oxazolidinone bromide
• Synonyms: (4S)-4-benzyl-3-<2-(triphenylphosphonio)acetyl>-2-oxazolidinone bromide
• CAS NO: 139278-12-9
• Molecular Weight: 560.427
• Mol File: 139278-12-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (4S)-4-benzyl-3-<2-(triphenylphosphonio)acetyl>-2-oxazolidinone bromide(CAS DataBase Reference)
• NIST Chemistry Reference: (4S)-4-benzyl-3-<2-(triphenylphosphonio)acetyl>-2-oxazolidinone bromide(139278-12-9)
• EPA Substance Registry System: (4S)-4-benzyl-3-<2-(triphenylphosphonio)acetyl>-2-oxazolidinone bromide(139278-12-9)

Safety Data

• Hazardous Substances Data: 139278-12-9(Hazardous Substances Data)

Upstream product

• 129549-13-9 4S-3-(2-bromoacetyl)-4-(phenylmethyl)-2-oxazolidinone 
• 603-35-0 triphenylphosphine 

Downstream Products

• 954419-90-0 (4S)-4-Benzyl-3-(4,4,4-trifluoro-3-methylbut-2-enoyl)oxazolidin-2-one 
• 139277-98-8 (4S)-4-benzyl-3-<(2E,5S,7E,9E)-5-(tert-butyldimethylsiloxy)-10-<(4R,6S,7R,8R,12R)-12-ethyl-7-methyl-2-oxo-6-(triethylsiloxy)-8-(triisopropylsiloxy)-1-oxacyclododec-4-yl>-2,7,9-decatrienoyl>-2-oxazolidinone 
• 218439-10-2 3-((4S)-4-phenylmethyl-2-oxazolidinoyl)carbonylmethylenetriphenylphosphorane 

Relevant articles and documents

A rapid access to both enantiomers of 1,2,3,4-tetranor B-trienic 18,18,18-trifluorosteroids. The first enantiocontrolled total synthesis of 18,18,18-trifluorosteroids

Chiral A-tetranor B-trienic 18,18,18-trifluorosteroid 2a and its enantiomer 1a were synthesised by the thermolysis of chiral olefinic benzocyclobutenes 7b and 7a which were in turn prepared by the aldol reaction of chiral oxazolidinone 5 and 11 with 2-(4-