139294-33-0

Basic information

• Product Name: Propanedioic acid, ethyl 2-[(phenylthio)methyl]-2-cyclopenten-1-yl ester
• CAS NO: 139294-33-0
• Molecular Formula: C17H20O4S
• Molecular Weight: 320.409
• Mol File: 139294-33-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Propanedioic acid, ethyl 2-[(phenylthio)methyl]-2-cyclopenten-1-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Propanedioic acid, ethyl 2-[(phenylthio)methyl]-2-cyclopenten-1-yl ester(139294-33-0)
• EPA Substance Registry System: Propanedioic acid, ethyl 2-[(phenylthio)methyl]-2-cyclopenten-1-yl ester(139294-33-0)

Safety Data

• Hazardous Substances Data: 139294-33-0(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 76047-52-4 2-<(phenylthio)methyl>cyclopent-2-en-1-one 
• 930-30-3 cyclopent-2-enone 
• 1071-46-1 hydrogen ethyl malonate 
• 139294-25-0 2--2-cyclopentene-1-ol 

Downstream Products

• 139294-49-8 8-Methylene-3-oxo-4-phenylsulfanyl-2-oxa-bicyclo[3.2.1]octane-4-carboxylic acid ethyl ester 
• 139294-41-0 2-Diazo-malonic acid ethyl ester 2-phenylsulfanylmethyl-cyclopent-2-enyl ester 

Relevant articles and documents

An Efficient and Convenient Synthesis of Bridged δ-Lactones

endo-4-Ethoxycarbonyl-4-(phenylthio)-9-methylene-2-oxabicyclononan-3-ones (5a-c) and their related compounds 5e-h, and endo-4-ethoxycarbonyl-4-(phenylthio)-8-methylene-2-oxabicyclooctan-3-one (5d) were synthesized from α-diazomalonates 3 of 2-(phenylthio)cyclohex-2-en-1-ols (1a-c) and their related compounds 1e-h, and 2-(phenylthio)cyclopent-2-en-1-ol (1d), respectively, via the sigmatropic rearrangement of cyclic allylsulfonium ylides 4.