1393670-72-8

Basic information

• Product Name: diethyl (1-(tert-butyl((4,4-dimethyl-5-oxotetrahydrofuran-3-yl)methoxy)amino)-2,2-dimethylpropyl)phosphonate
• Synonyms: diethyl (1-(tert-butyl((4,4-dimethyl-5-oxotetrahydrofuran-3-yl)methoxy)amino)-2,2-dimethylpropyl)phosphonate
• CAS NO: 1393670-72-8
• Molecular Weight: 421.514
• Mol File: 1393670-72-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: diethyl (1-(tert-butyl((4,4-dimethyl-5-oxotetrahydrofuran-3-yl)methoxy)amino)-2,2-dimethylpropyl)phosphonate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl (1-(tert-butyl((4,4-dimethyl-5-oxotetrahydrofuran-3-yl)methoxy)amino)-2,2-dimethylpropyl)phosphonate(1393670-72-8)
• EPA Substance Registry System: diethyl (1-(tert-butyl((4,4-dimethyl-5-oxotetrahydrofuran-3-yl)methoxy)amino)-2,2-dimethylpropyl)phosphonate(1393670-72-8)

Safety Data

• Hazardous Substances Data: 1393670-72-8(Hazardous Substances Data)

Upstream product

• 1393670-68-2 allyl 2-((tert-butyl(1-(diethoxyphosphoryl)-2,2-dimethylpropyl)amino)oxy)-2-methylpropanoate 

Relevant articles and documents

Direct functionalization of labile alkoxyamines

Direct esterification of a labile alkoxyamine R1R 2NOR3, which was previously reported as unsuccessful, is achieved by a Mitsunobu reaction or a nucleophilic substitution. Ester derivatives are obtained under smooth conditions and easily purified. Macrocyclization attempts on ester derivatives were successful for five-membered ring lactones and unsuccessful for 13-membered ring lactones. Moreover, the success of the cyclization was dramatically dependent on the quality of the solution degassing. Poor degassing led to unexpected carbonate alkoxyamine.