1393674-58-2Relevant academic research and scientific papers
Catalytic epoxidation of stilbenes with non-peripherally alkyl substituted carbonyl ruthenium phthalocyanine complexes
Enow, Charles A.,Marais, Charlene,Bezuidenhoudt, Barend C.B.
, p. 403 - 412 (2012)
A number of novel carbonyl(1,4,8,11,15,18,22,25-octaalkylphthalocyaninato)- ruthenium(II) complexes were prepared by metal insertion with Ru 3(CO)12. The new compounds have been characterized by 1H NMR, 13C NMR, IR, UV-vis and mass spectroscopy. This study demonstrated that this type of complexes and specifically carbonyl(1,4,8,11,15,18,22,25-octahexylphthalo-cyaninato)ruthenium(II) and carbonyl[1,4,8,11,15,18,22,25-octa(2-cyclohexylethyl)phthalocyaninato] -ruthenium(II), exhibit high catalytic activity and stability in the epoxidation of stilbenes with 2,6-dichloropyridine N-oxide as oxidant.
