139386-55-3Relevant academic research and scientific papers
Oxovanadium(IV) complex-mediated catalysis in Mukaiyama-type aldol additions
Chen, Chien-Tien,Hon, Sang-Wen,Weng, Shiue-Shien
, p. 816 - 818 (1999)
Condensation of vanadyl sulfate with 2,2'-biphenol in the presence of N- containing ligands provides oxovanadium(IV) complexes which serve as efficient catalysts in Mukaiyama aldol reactions to afford aldol products in 52-100% yields with diastereoselecti
syn-Selective Aldol Reaction of Propynal-Hexacarbonylcobalt Complexes with Ketene Silyl Acetals
Mukai, Chisato,Suzuki, Kimimasa,Nagami, Kazuyoshi,Hanaoka, Miyoji
, p. 141 - 146 (2007/10/02)
3-Phenylpropynal-hexacarbonylcobalt complex, prepared from 3-phenylpropynal with octacarbonylcobalt, afforded on treatment with the seven-membered ketene trimethylsilyl acetal the syn-aldol product in a highly stereoselective manner.Similar exposure of th
