1393879-05-4Relevant academic research and scientific papers
A method of manufacturing a silyl ether compd. hydroxyacid
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Paragraph 0078; 0085, (2016/12/22)
PROBLEM TO BE SOLVED: To provide a method for obtaining a hydroxysilyl ether compound by turning one hydroxy group out of two hydroxy groups of a diol compound into a silyl ether. SOLUTION: In the method for producing a hydroxysilyl ether compound in good yield, the objective compound is prepared by reacting, in an organic solvent, the diol compound (e.g., cis-1,2-cyclooctanediol (cyclic 1,2-diol compound)) selected from a cyclic 1,2-diol compound, a chain 1,2-diol compound and chain 1,3-diol compound with an organic silicon halide compound in the presence of a Lewis acid catalyst and an organic base. COPYRIGHT: (C)2012,JPOandINPIT
Scaffolding catalysts: Highly enantioselective desymmetrization reactions
Sun, Xixi,Worthy, Amanda D.,Tan, Kian L.
supporting information; experimental part, p. 8167 - 8171 (2011/10/18)
Ex-changing places: A highly enantioselective desymmetrization of 1,2-diols has been developed in which the catalyst utilizes reversible covalent bonding to the substrate to achieve both high selectivity and rate acceleration (see scheme, PMP=pentalmethyl
