1394035-47-2Relevant articles and documents
Rhodium-catalyzed asymmetric coupling reaction of allylic ethers with arylboronic acids
Kiuchi, Hiroyoshi,Takahashi, Dai,Funaki, Kenji,Sato, Tetsuo,Oi, Shuichi
supporting information, p. 4502 - 4505 (2012/10/29)
An asymmetric allylic substitution of simple allylic ethers with arylboronic acids in the presence of a rhodium(I)/(R)-DTBM-SEGPHOS catalyst has been developed. The reactions proceeded smoothly at room temperature to give the corresponding branch products with excellent regioselectivities and good to excellent enantioselectivities.