139407-08-2

Basic information

• Product Name: (2S,3S,4S)-4-isopropenyl-3-methoxycarbonylmethyl-pyrrolidine-1,2-dicarboxylic acid 1-tert-butyl ester 2-methyl ester
• CAS NO: 139407-08-2
• Molecular Weight: 341.404
• Mol File: 139407-08-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (2S,3S,4S)-4-isopropenyl-3-methoxycarbonylmethyl-pyrrolidine-1,2-dicarboxylic acid 1-tert-butyl ester 2-methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S,4S)-4-isopropenyl-3-methoxycarbonylmethyl-pyrrolidine-1,2-dicarboxylic acid 1-tert-butyl ester 2-methyl ester(139407-08-2)
• EPA Substance Registry System: (2S,3S,4S)-4-isopropenyl-3-methoxycarbonylmethyl-pyrrolidine-1,2-dicarboxylic acid 1-tert-butyl ester 2-methyl ester(139407-08-2)

Safety Data

• Hazardous Substances Data: 139407-08-2(Hazardous Substances Data)

Upstream product

• 487-79-6 (-)-kainic acid 

Downstream Products

• 487-79-6 (+/-)-α-kainic acid 
• 103314-33-6 (2S,3S,4S)-3-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-2-(tert-butyl-dimethyl-silanyloxymethyl)-4-{(E)-4-oxo-1-[phenylsulfanyl-(2,2,2-trifluoro-acetoxy)-methyl]-pent-2-enyl}-pyrrolidine-1-carboxylic acid tert-butyl ester 
• 103314-32-5 (2S,3S,4S)-4-((E)-1-Benzenesulfinylmethyl-4-oxo-pent-2-enyl)-3-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-2-(tert-butyl-dimethyl-silanyloxymethyl)-pyrrolidine-1-carboxylic acid tert-butyl ester 
• 103314-31-4 (2S,3S,4S)-3-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-2-(tert-butyl-dimethyl-silanyloxymethyl)-4-((E)-4-oxo-1-phenylsulfanylmethyl-pent-2-enyl)-pyrrolidine-1-carboxylic acid tert-butyl ester 
• 115268-37-6 (2S,3S,4S)-4-((Z)-1-Acetyl-4-phenylsulfanyl-but-1-enyl)-3-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-2-(tert-butyl-dimethyl-silanyloxymethyl)-pyrrolidine-1-carboxylic acid tert-butyl ester 
• 103314-30-3 (2S,3S,4S)-3-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-2-(tert-butyl-dimethyl-silanyloxymethyl)-4-(1-formyl-2-phenylsulfanyl-ethyl)-pyrrolidine-1-carboxylic acid tert-butyl ester 
• 86630-10-6 acromelic acid B 
• 86630-09-3 Acromelic acid A 
• 487-79-6 (-)-kainic acid 

Relevant articles and documents

Synthesis of kainoids via a highly stereoselective hydroformylation of kainic acid

An efficient preparation of a series of secondary amines, structurally related to the kainic acid scaffold, is described. Naturally occurring (-)-α-kainic acid was hydroformylated with complete terminal selectivity and high stereoselectivity. The stereoch

Palladium-Catalysed Vinylic Substitution of Dimethyl Esters of N-Alkoxycarbonylkainic Acids with Aryl Halides

The palladium-catalysed reaction of dimethyl esters of N-alkoxycarbonylkainic acids with aryl halides in the presence of catalytic amounts of Pd(OAc)2 and of the n-Bu4NCl/NaHCO3 combination affords stereoselectively the co

SYNTHESIS OF ACROMELIC ACID A, A TOXIC PRINCIPLE OF CLITOCYBE ACROMELALGA.

Acromelic acid A, a toxic principle of Clitocybe acromelalga, was synthesized from L-α-kainic acid.The synthesis established the previously inferred structure, and determined the absolute configuration as shown by 1.